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991.
Dongdong Wang Ruilin Zheng Zhongyue Wang Weiyan Yue Zhao Quan Bo Peng Wei Wei 《Journal of the American Ceramic Society》2014,97(9):2909-2914
A kind of novel CaF2:Nd microcrystal‐glass composites with high transmittance and long fluorescence lifetime were prepared by a two‐step melt‐quenching technique. Based on Mie theory, a theoretical estimate of the scattering losses was suggested for the microcrystal‐glass composites. By matching dispersion curve of the glass matrix and CaF2 microcrystal in the range of UV–Vis‐NIR, the transmittance can reach 83%. The effects of CaF2:Nd microcrystals/glass ratio on structure and optical properties were investigated. The composite sample‐doped 30 wt% CaF2:Nd nano/microcrystals exhibits long fluorescence lifetime of 518 μs at 1051 nm. 相似文献
992.
Wei‐Hsiang Hsu Hsing‐I Hsiang Ming‐Hung Chen Chih‐Cheng Chen 《Journal of the American Ceramic Society》2014,97(8):2439-2446
CuInSe2 (CIS) powders were synthesized using CuSe, Cu2Se, and In2Se3 as the raw materials. The formation mechanisms and reaction kinetics from CuSe/In2Se3 and Cu2Se/In2Se3 powders in a selenium atmosphere were investigated. It was observed that the formation temperature of α‐CIS powders synthesized using Cu2Se/In2Se3 as the raw materials was higher than that using CuSe/In2Se3. Both reactions for Cu2Se/In2Se3 and CuSe/In2Se3 mixtures follow one‐dimensional diffusion‐controlled reactions with apparent activation energies of 124.3 and 73.2 kJ/mol, respectively. For both mixtures the indium‐rich β‐CIS phase resulting from Cu+ ion diffusion toward the In2Se3 phase was observed. The particle size and morphology of the newly formed CIS was similar to In2Se3, which indicated that the CIS formation kinetics may be dominated by the diffusion of Cu+ ions. The Cu–Se liquid phase resulting from the peritectic decomposition of CuSe2 and CuSe at a relatively low temperature may promote Cu+ diffusion into the In2Se3 surface, assisting CIS formation. 相似文献
993.
Shuangqing Xu Qin Cheng Wei Li Jinli Zhang 《American Institute of Chemical Engineers》2014,60(3):1143-1155
Hydrodynamics of a pilot‐scale in‐line high shear mixer (HSM) with double rows of ultrafine rotor and stator teeth, including the velocity profiles and power consumptions, were measured using laser Doppler anemometry and a torque transducer, respectively. Computational fluid dynamics simulations were conducted using the standard k‐ε turbulence model with first‐ and second‐order accuracy and large eddy simulation (LES) with the standard Smagorinsky–Lilly subgrid scale model. Predictive capabilities of the different turbulence models and discretization schemes were assessed based on the experimental data. It is found that the current LES can predict accurately the flow patterns for the strongly rotating and locally anisotropic turbulent flows in the complex in‐line HSM. The results obtained are fundamental to explore potential applications of the in‐line teethed HSMs to intensify chemical reaction processes. © 2013 American Institute of Chemical Engineers AIChE J, 60: 1143–1155, 2014 相似文献
994.
Xuebin Qiao Jing Wang Yanlin Huang Peiqing Cai Sun I. L. Kim Hyo‐Jin Seo 《Journal of the American Ceramic Society》2014,97(11):3561-3567
Eu2+‐doped zinc fluoro‐phosphate Zn2[PO4]F was synthesized by the conventional high‐temperature solid‐state reaction. The phase formation was confirmed by X‐ray powder diffraction measurements and the structure refinement. The photoluminescence excitation and emission spectra, and the decay curves were measured. The natures of the Eu2+ emission in inorganic hosts, e.g., the emission and excitation properties, the chromaticity coordinates, the Stokes shifts, the absolute quantum efficiency, and the luminescence thermal stability were reported. Under the excitation of near‐UV light, Eu2+‐doped Zn2[PO4]F presents a narrow blue‐emitting band centered at 423 nm. The thermal stability of the blue luminescence was evaluated by the luminescence intensities as a function of temperature. The phosphor shows an excellent thermal stability on temperature quenching effects. 相似文献
995.
Zhao Han Jun Liu Xiao‐Wei Li Yi‐Xiang Chen Guang‐Hua Liu Jiang‐Tao Li 《Journal of the American Ceramic Society》2014,97(9):2705-2708
The present study describes the successful synthesis of a Ca2+‐doped LaCrO3 ceramic with high infrared (IR) emissivity, which is important for high‐temperature applications for significant energy saving. It is demonstrated that 20 mol% Ca2+‐doped LaCrO3, i.e., La0.8Ca0.2CrO3, exhibited an IR emissivity as high as 0.95 in the spectral region of 3–5 μm, which was 33.8% higher than that of LaCrO3. By using La0.8Ca0.2CrO3 as IR radiation agent in surface coating of heating unit, the radiative heat transfer could be enhanced significantly. The mechanism of the high IR emissivity of La0.8Ca0.2CrO3 was attributed to the following aspects: Ca2+ doping introduced an impurity energy level of Cr4+ into LaCrO3 and increased the hole carrier concentration, enhancing both impurity absorption and hole carrier absorption in the IR region; moreover, the doping caused lattice distortion enhanced the lattice vibration absorption. This novel high IR emissivity ceramic shows a promising future in high‐temperature applications for the purpose of energy‐saving. 相似文献
996.
Wei‐Ming Guo Yang You Shang‐Hua Wu Hua‐Tay Lin 《Journal of the American Ceramic Society》2014,97(5):1359-1362
TiB2 powders were synthesized by borothermal reduction in nanoscale TiO2 with boron under vacuum. Reaction processes were investigated, and the effect of by‐product B2O3 was evaluated. Results showed that TiO2 was firstly reduced by boron to form TiBO3 and Ti2O3, and then to produce TiB2 and B2O3 with increasing temperature. The reaction processes of TiB2 powders synthesis included two‐step reduction in TiO2 by boron and the removal of B2O3. The presence of B2O3, which was previously reported as the most important factor in promoting the coarsening of ZrB2 and HfB2 powders by borothermal reduction, did not lead to significant coarsening of TiB2 powders. Due to the minor effect of B2O3, TiB2 powders with small particle size and low oxygen content could be prepared by direct heat treatment of TiO2 and boron at 1550°C under vacuum for 1 h. The particle size and oxygen content of synthesized TiB2 powders were ~0.9 μm and ~1.7 wt%, respectively. 相似文献
997.
998.
999.
和传统的钢护拦相比较,竹片增强复合材料护拦具有重量轻、成本低、耐腐蚀、环境友善和可再生性等优点。但是竹纤维表面的复杂成分,影响了复合材料的界面性能。本文利用竹片作为增强材料,采用真空辅助成型方法制备了竹片增强环氧乙烯基树脂复合材料,研究了表面改性和铺层数对竹复合材料弯曲强度和冲击韧性的影响,并对单向复合材料的冲击断面破坏方式进行了分析。结果表明,在不同铺层结构条件下,用经过碱与硅烷偶联剂改性处理过的竹条制备的复合材料的弯曲强度分别提高了31.95%、46.72%、29.58%,冲击韧性分别提高了25.62%、29.74%、28.61%,而且单向复合材料的弯曲和冲击性能最佳。当单向复合材料中的竹片铺层为15层时,其冲击吸收功为13.55J,拉伸强度为270MPa,弯曲强度为340MPa,在主要性能上能满足公路防撞护栏对其原料Q-235B钢的要求;通过扫描电镜分析发现,竹片增强复合材料防撞护栏材料的防撞机理表现为竹纤维抽拔断裂、基体断裂、纤维/基体界面脱黏以及剪切分层。本文的结果对复合材料公路防撞护栏的制备有一定的指导作用。 相似文献
1000.